The Man Who Thought His Wife Was a Hat - which is a collection of stories of rare neurological disorders. The titular story is a man whose brain would make bizarre associations, and in that case he was leaving the doctor's office and looked at his wife, and his brain went "My wife>my wife's head>hats go on heads>that must be a hat" and he literally tried to grab his wife's head with the intention of wearing it.
Surely You're Joking, Mr. Feynman - Richard Feynman was a theoretical physicist and one of the great scientific minds of his generation, but he was also very witty and a great storyteller. His autobiography is a really easy and interesting read.
Madam Secretary - The autobiography of Madeleine Albright, who was the first female Secretary of State.
Jack Welch and the G.E. Way - a great business book.
Opening The Xbox - the story of how Microsoft decided to build their gaming console. At the time, there was a big internal debate about whether to focus their available resources on video games, or WEBTV (which was a device for accessing the Internet through your TV, back in the days of dial-up.)
The Weather Channel - The story of how they conceived and implemented a national weather channel on TV. It's a dry topic, but it's full of stories about making complicated deals and negotiations to get information flowing from state to state, back before there was an Internet to speak of.